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Spectrele de infrarosu si ipoteza cuantica


As result of IR photon acting over a molecule the following motions for an atom or a group of atoms is possible:
• symmetrical stretching
infrared07
• antisymmetrical stretching
infrared08
• scissoring
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• rocking

• wagging

• twisting


Why the actual explanation is absurd…..

It is necessary in a first step to evaluate the effects of quite equal infrared photon energy in the up presented cases.
In case of hydrogen atom the IR photon produces only a flip of electron from an orbit (or orbital) to another orbit (or orbital) as in fig. 1. The IR radiation is not strong enough to move the entire atom and in fact all quantum mechanics theories admit the immobility of nucleus during electron jump. If the IR photon hit directly the hydrogen nucleus, there is no enough energy to have a macroscopic effect.
But what’s happened in case of IR molecule spectra?
Quite the same IR energies produce an unimaginable result. An entire atom (electrons and nucleus), or an entire groups of atoms execute different kinds of movements from stretching to twisting.
It is possible to accept as real this atom or group of atoms change of position?
If we keep the proportion and translate the phenomena to the real world it is similar to saying that a fly knock a car and the car is forced to leave the road.
If a correlation between effects of IR and X-ray photons is made, other vexatious problems appear looking in the frame of quantum mechanics.
An X-ray photon is able to liberate electrons from a material. Why X-ray is not able to liberate an entire nucleus? Why a IR energy photon is able to move an atom but is not able to liberate an electron from a material?
If an IR photon is able to move an atom, it should be observed how an X-ray or gamma ray, with a greater energy, should expel an entire nucleus.
On the other hand, does anyone asks how is possible for an atom (with its layers of electrons)  jump ,,in a single step" from one position to another position? For a simple electron, when make a jump between two layers it can be admitted, according to quantum mechanic, the single step movement or cuanta of action. For an entire atom it is quite impossible to have a single step process. Up to date, there are no scientific texts which treat in detail this subject – quantum atomic jump – so the quantum theoreticians can use their imagination in order to fill this void.
In proposed theory as was already highlighted the quantum hypothesis is ruled out. In the same time there is a correlation between energy of incident photons and the observed effects and the spectra needs a new interpretation.

 

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